142799-37-9Relevant academic research and scientific papers
A stable compound with a formal tin-carbon double bond: The bis(2,4,6-triisopropylphenyl)(fluorenylidene)stannene
Anselme,Ranaivonjatovo,Escudié,Couret,Satgé
, p. 2748 - 2750 (2008/10/08)
Bis(2,4,6-triisopropylphenyl)(fluorenylidene)-stannene-diethyl ether (1a), a new stable compound with a formal tin-carbon double bond, has been synthesized by dehydrofluorination of the corresponding fluoro-stannane with tert-butyllithium; it has been characterized by NMR (δ(119Sn) + 288 ppm, δ(13C) +133.85 ppm) and UV spectroscopy (λmax 542 nm) and by electrophilic addition reactions to the tin-carbon unsaturation.
