1428102-00-4Relevant articles and documents
Isomerism of a series of octahedrally coordinated transition metal carboxylate-phosphinates with 1,10-phenanthroline as a coligand: Discrete dimers or double-chains constructed by various dimeric ring motifs
Zhao, Cui-Cui,Zhou, Zhong-Gao,Xu, Xiang,Dong, Li-Jie,Xu, Guo-Hai,Du, Zi-Yi
, p. 18 - 26 (2013)
Six octahedrally coordinated transition metal carboxylate-phosphinates with 1,10-phenanthroline (phen) as a coligand, namely [Mn(L)(phen)(H 2O)]·2(H2O) (1), [Mn(L)(phen)(H2O)] (2), [Cu(L)(phen)(H2O)]·3(H2O) (3), [Cd(L)(phen)] (4), [Cd(L)(phen)]·3(H2O) (5) and [Cd(L)(phen)]·13/6(H 2O) (6) (L2- = (2-carboxyethyl)(phenyl)phosphinate) are presented here, of which 1 and 3 show discrete dimer structures while 2, 4, 5 and 6 feature different double-chain arrays. Compounds 1 and 2, as well as 4, 5 and 6, can be regarded as isomers, and 3 bears a strong structural analogy to 1, although the metal species in them are different.