1428369-75-8Relevant academic research and scientific papers
Construction of monocyclic eight-membered rings: Intermolecular rhodium(I)-catalyzed [6+2] cycloaddition of 4-allenals with alkynes
Oonishi, Yoshihiro,Hosotani, Akihito,Sato, Yoshihiro
, p. 11548 - 11551 (2013/01/15)
Rounding up: A RhI-catalyzed intermolecular cycloaddition of 4-allenals with alkynes has been developed that provides various monocyclic eight-membered rings in good to high yields in a stereoselective manner (see scheme). In addition, the chirality of the starting allene is transferred in this reaction, thereby giving optically active monocyclic eight-membered ring compounds. Copyright
