1428377-96-1

Basic information

• Product Name: 1,4-diphenyl-1-vinylcyclohexane
• CAS NO: 1428377-96-1
• Molecular Weight: 262.395
• Mol File: 1428377-96-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-diphenyl-1-vinylcyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-diphenyl-1-vinylcyclohexane(1428377-96-1)
• EPA Substance Registry System: 1,4-diphenyl-1-vinylcyclohexane(1428377-96-1)

Safety Data

• Hazardous Substances Data: 1428377-96-1(Hazardous Substances Data)

Upstream product

• 1240401-98-2 2-(4-phenylcyclohexylidene)ethyl picolinate 
• 100-58-3 phenylmagnesium bromide 

Relevant articles and documents

Allylic substitution for construction of a chiral quaternary carbon possessing an aryl group

Phenylcopper reagents derived from 2:1 PhMgBr/Cu(acac)2 and 3:1:1 PhMgBr/Cu(acac)2/ZnI2 were found to be highly reactive and regioselective in the allylic substitution of γ,γ- disubstituted secondary allylic picolinates designed for construction of a quaternary carbon, whereas the previous 2:1 ArMgBr/CuBr·Me2S reagent and that with ZnX2 were unsuccessful. The generality of the ArMgBr/Cu(acac)2 reagent was examined with enantiomerically enriched allylic picolinates, which furnished quaternary carbons with high efficiency in >92% regioselectivity and >97% chirality transfer. Two cyclohexanes with a quaternary carbon were synthesized by using these reagents.