1428476-55-4Relevant articles and documents
Asymmetric methallylation of ketones catalyzed by a highly active organocatalyst 3,3′-F2-BINOL
Zhang, Yongda,Li, Ning,Qu, Bo,Ma, Shengli,Lee, Heewon,Gonnella, Nina C.,Gao, Joe,Li, Wenjie,Tan, Zhulin,Reeves, Jonathan T.,Wang, Jun,Lorenz, Jon C.,Li, Guisheng,Reeves, Diana C.,Premasiri, Ajith,Grinberg, Nelu,Haddad, Nizar,Lu, Bruce Z.,Song, Jinhua J.,Senanayake, Chris H.
supporting information, p. 1710 - 1713 (2013/06/27)
(S)-3,3′-F2-BINOL has been synthesized for the first time and demonstrated as a highly active organocatalyst for asymmetric methallylation of ketones. Up to 98:2 enantioselectivity and 99% yield were obtained with 5 mol % catalyst loading. The