1428744-69-7

Upstream product

• 21947-87-5 L-diisopinocampheylborane 

Downstream Products

• 1428744-60-8 (1S,2S,E)-4-(dimethyl(phenyl)silyl)-2-methyl-1-phenylbut-3-en-1-ol 
• 1428744-67-5 (2S,3S,E)-1-(benzyloxy)-5-(dimethyl(phenyl)silyl)-3-methylpent-4-en-2-ol 
• 1428744-65-3 (1R,2S,E)-1-cyclohexyl-4-(dimethyl(phenyl)silyl)-2-methylbut-3-en-1-ol 
• 1428744-64-2 (3R,4S,E)-6-(dimethyl(phenyl)silyl)-4-methyl-1-phenylhex-5-en-3-ol 
• 1428744-63-1 (1E,3R,4S,5E)-6-(dimethyl(phenyl)silyl)-4-methyl-1-phenylhexa-1,5-dien-3-ol 
• 1440422-48-9 (3S,4R,6R,7R,E)-8-((tert-butyldiphenylsilyl)oxy)-1-(dimethyl(phenyl)silyl)-6-methoxy-3,7-dimethyloct-1-en-4-ol 
• 1428744-62-0 (1R,2R,E)-4-(dimethyl(phenyl)silyl)-2-methyl-1-phenylbut-3-en-1-ol 
• 1428744-61-9 (1S,2R,E)-4-(dimethyl(phenyl)silyl)-2-methyl-1-phenylbut-3-en-1-ol 

Relevant academic research and scientific papers

Enantioselective synthesis of (E)-δ-silyl-anti-homoallylic alcohols via an enantiodivergent hydroboration-crotylboration reaction of a racemic allenylsilane

The enantioselective hydroboration of racemic allenylsilane (±)-4 with (dIpc)2BH proceeds via enantiodivergent pathways to give vinylborane 11 and crotylborane intermediate (S)-E-5. Subsequent crotylboration of aldehyde substrates with (S)-E-5 at -78 C provides (E)-δ-silyl-anti-homoallylic alcohols in 71-89% yield and with 93-96% ee.