1429033-70-4

Basic information

• Product Name: (R)-1-[(4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylbut-3-en-2-yl methyl carbonate
• Synonyms: (R)-1-[(4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylbut-3-en-2-yl methyl carbonate
• CAS NO: 1429033-70-4
• Molecular Weight: 512.718
• Mol File: 1429033-70-4.mol

Chemical Properties

• CAS DataBase Reference: (R)-1-[(4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylbut-3-en-2-yl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-[(4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylbut-3-en-2-yl methyl carbonate(1429033-70-4)
• EPA Substance Registry System: (R)-1-[(4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylbut-3-en-2-yl methyl carbonate(1429033-70-4)

Safety Data

• Hazardous Substances Data: 1429033-70-4(Hazardous Substances Data)

Upstream product

• 171232-50-1 [(4S,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetaldehyde 
• 1429033-45-3 (R)-1-[(4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylbut-3-en-2-ol 
• 79-22-1 methyl chloroformate 

Relevant articles and documents

A stereoconvergent intramolecular Diels-Alder cycloaddition related to the construction of the decalin core of neo-clerodane diterpenoids

Several examples of a highly specific, stereoconvergent intramolecular Diels-Alder cycloaddition that led to the trans-decalin core of neo-clerodane diterpenoids are described. The relative configuration adjacent to the dienophile, which led to C4 of the decalin system, as well as the electron-withdrawing effects of various substituents and conformational rigidity of the Diels-Alder precursors were explored.