1429043-31-1

Basic information

• Product Name: 1-[1-(3-chloromethyl)phenyl(methyl)]-4-[2,6-dimethylphenyl]-1,2,4-4H-triazol-1-ium chloride
• CAS NO: 1429043-31-1
• Molecular Weight: 348.275
• Mol File: 1429043-31-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[1-(3-chloromethyl)phenyl(methyl)]-4-[2,6-dimethylphenyl]-1,2,4-4H-triazol-1-ium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[1-(3-chloromethyl)phenyl(methyl)]-4-[2,6-dimethylphenyl]-1,2,4-4H-triazol-1-ium chloride(1429043-31-1)
• EPA Substance Registry System: 1-[1-(3-chloromethyl)phenyl(methyl)]-4-[2,6-dimethylphenyl]-1,2,4-4H-triazol-1-ium chloride(1429043-31-1)

Safety Data

• Hazardous Substances Data: 1429043-31-1(Hazardous Substances Data)

Upstream product

• 1245737-20-5 4-(2,6-dimethylphenyl)-4H-1,2,4-triazole 
• 626-16-4 3-(chloromethyl)benzyl chloride 

Relevant articles and documents

Stepwise deprotonation of a thiol-functionalized bis(1,2,4-triazolium) salt as a selective route to heterometallic NHC complexes

Heterometallic NHC complexes have been selectively prepared at room temperature directly from an azolium salt in a two-step procedure. In the unsymmetrically substituted bis(1,2,4-triazolium) ligand precursor, one of the m-xylylene-bridged triazolium units features an unprotected o-thiophenol substituent. This renders possible a selective deprotonation and in situ monopalladation at the NHC-thiolato unit. The obtained palladium(II) complex possesses two pendant triazolium units as vacant binding sites. After a second deprotonation/metalation step, a heterodinuclear palladium(II) gold(I) complex and a heterotrinuclear palladium(II) dicopper(I) complex were obtained. In the latter, two metal centers are connected via a thiolato bridge.