1429063-84-2Relevant academic research and scientific papers
New acetyl-containing aromatic polyether with perfluorinated mono- and biphenylene fragments
Tkachenko, Igor M.,Purikova, Olga G.,Shekera, Oleg V.,Shevchenko, Valery V.
, p. 77 - 78 (2016)
A novel fluorinated poly(arylene ether) containing tetrafluorobenzene and octafluorobenzene fragments and acetyl side groups was synthesized by polycondensation of 1,4-bis(3-acetyl-4-hydroxyphenoxy)-2,3,5,6-tetrafluorobenzene and decafluorobiphenyl. Some properties of this polymer were examined, and its keto groups were reduced into alcohol ones.
Fluorinated allyl-, acetyl-, and bromo-containing hydroxyl-substituted phenyl ethers with a hexafluorobenzene or decafluorobiphenyl central unit
Tkachenko, Igor,Shekera, Oleg,Bliznyuk, Valery,Shevchenko, Valery
, p. 36 - 41 (2013/05/09)
We report on methods of synthesis of new hexafluorobenzene- and decafluorobiphenyl-based hydroxyl-substituted phenyl ethers containing allyl, acetyl groups, and bromine atoms. Optimal conditions for Claisen and Fries rearrangements used during the synthesis of these fluorinated compounds are discussed. The resulting compounds can be employed as monomers for synthesis of a wide variety of nucleus-fluorinated aromatic polymers suitable for optical or membrane applications.
