1429207-05-5

Basic information

• Product Name: ethyl 7-((2-(hydroxymethyl)phenyl)amino)hept-2-enoate
• CAS NO: 1429207-05-5
• Molecular Weight: 277.364
• Mol File: 1429207-05-5.mol

Chemical Properties

• CAS DataBase Reference: ethyl 7-((2-(hydroxymethyl)phenyl)amino)hept-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 7-((2-(hydroxymethyl)phenyl)amino)hept-2-enoate(1429207-05-5)
• EPA Substance Registry System: ethyl 7-((2-(hydroxymethyl)phenyl)amino)hept-2-enoate(1429207-05-5)

Safety Data

• Hazardous Substances Data: 1429207-05-5(Hazardous Substances Data)

Upstream product

• 5344-90-1 2-Aminobenzyl alcohol 
• 59612-36-1 ethyl 6-formylhex-2-enoate 

Relevant articles and documents

Metal-free α-amination of secondary amines: Computational and experimental evidence for azaquinone methide and azomethine ylide intermediates

We have performed a combined computational and experimental study to elucidate the mechanism of a metal-free α-amination of secondary amines. Calculations predicted azaquinone methides and azomethine ylides as the reactive intermediates and showed that iminium ions are unlikely to participate in these transformations. These results were confirmed by experimental deuterium-labeling studies and the successful trapping of the postulated azomethine ylide and azaquinone methide intermediates. In addition, computed barrier heights for the rate-limiting step correlate qualitatively with experimental findings.