142926-35-0Relevant articles and documents
Asymmetric epoxidation catalyzed by novel azacrown ether-type chiral quaternary ammonium salts under phase-transfer catalytic conditions
Hori, Kazushige,Tamura, Mina,Tani, Keita,Nishiwaki, Nagatoshi,Ariga, Masahiro,Tohda, Yasuo
, p. 3115 - 3118 (2006)
Asymmetric epoxidation of (E)-chalcone with alkaline hydrogen peroxide by novel chiral phase-transfer catalysts (chiral PTCs) with quaternary ammonium salts of azacrown ether proceeded in high yield and good enantioselectivity. Remarkably, this reaction d
Synthesis of chiral crown ethers having bromoarylene moieties on their rim. Anomalous behavior of racemic substrates in cyclization to crown ethers
Kiyooka, Syun-Ichi,Tada, Mitsuhiro,Kan, Sachie,Fujio, Mizue
, p. 2595 - 2601 (2007/10/03)
Bis(binaphtho)-22-crown-5 and bis(binaphtho)-22-crown-4, having bromoarylene moities on their rim, were prepared from (R)- and (5)-2,2′-dihydroxy-1,1′-binaphthyl. An acyclic diol, bridged by two (R)-binaphthyl moieties, underwent cyclization reaction with