1429342-65-3Relevant academic research and scientific papers
Enhancing the anion affinity of urea-based receptors with a Ru(terpy) 22+ chromophore
Baggi, Giorgio,Boiocchi, Massimo,Ciarrocchi, Carlo,Fabbrizzi, Luigi
, p. 5273 - 5283 (2013)
Covalent linking of a Ru(terpy)22+ substituent improves recognition and sensing properties of the urea subunit toward anions. Urea's anion affinity is enhanced by the electrostatic attraction exerted by the RuII cation and by the electron-withdrawing effect exerted by the entire polypyridine-metal complex. Such an enhancement of the anion affinity, which results from the combination of a through-space and a through-bond effect, is greater than that exerted by the classical neutral electron-withdrawing substituent nitrophenyl. Small yet significant modifications of π-π* and MLCT bands of the Ru(terpy)22+ chromophore, detected through UV-vis spectrophotometric titrations, allowed the determination of the constants for the formation of receptor-anion H-bond complexes in diluted MeCN solution. On 1H NMR titration experiments, carried out under more concentrated conditions, the interaction of a second Cl- ion was observed, taking place through an outer-sphere mechanism. The Ru(terpy) 22+ substituent favors the deprotonation of a urea N-H fragment on addition of a second equivalent of fluoride, with formation of HF2-.
