1429373-35-2Relevant articles and documents
Asymmetric Carboxycyanation of Aldehydes by Cooperative AlF/Onium Salt Catalysts: from Cyanoformate to KCN as Cyanide Source
Brodbeck, Daniel,álvarez-Barcia, Sonia,Meisner, Jan,Broghammer, Florian,Klepp, Julian,Garnier, Delphine,Frey, Wolfgang,K?stner, Johannes,Peters, René
, p. 1515 - 1524 (2019)
Asymmetric 1,2-additions of cyanide yield enantioenriched cyanohydrins as versatile chiral building blocks. Next to HCN, volatile organic cyanide sources are usually used. Among them, cyanoformates are more attractive on technical scale than TMSCN for cos
Bifunctional Schiff base/Ti(IV) catalysts for enantioselective cyanoformylation of aldehydes with ethyl cyanoformate
Ji, Nan,Yao, Lin,He, Wei,Li, Yurong
, p. 209 - 213 (2013/05/08)
A new bifunctional titanium/Schiff base catalyst was developed for the enantioselective cyanoformylation of aldehydes with ethyl cyanoformate. The reaction proceeded smoothly with a mild reaction condition to afford the cyanohydrin ethyl carbonates in hig