1429426-19-6

Basic information

• Product Name: C₆₁H₆₇N₃O₈P₂Pt
• CAS NO: 1429426-19-6
• Molecular Weight: 1227.25
• Mol File: 1429426-19-6.mol

Chemical Properties

• CAS DataBase Reference: C₆₁H₆₇N₃O₈P₂Pt(CAS DataBase Reference)
• NIST Chemistry Reference: C₆₁H₆₇N₃O₈P₂Pt(1429426-19-6)
• EPA Substance Registry System: C₆₁H₆₇N₃O₈P₂Pt(1429426-19-6)

Safety Data

• Hazardous Substances Data: 1429426-19-6(Hazardous Substances Data)

Upstream product

• 1429426-20-9 2,6-bis(13-(diphenylphosphino)-2,5,8,11-tetraoxatridecyl)pyridine 
• 2510-22-7 4-pyridylacetylene 
• 1429426-21-0 C₄₇H₅₉Cl₂NO₈P₂Pt 
• 1416728-99-8 1,1'-(pyridine-2,6-diyl)bis(2,5,8,11-tetraoxatridecane-13,1-diyl) dimethanesulfonate 
• 236109-12-9 1,1'-(pyridine-2,6-diyl)bis(2,5,8,11-tetraoxatridecan-13-ol) 
• 1416728-96-5 2,6-bis(13-((tetrahydro-2H-pyran-2-yl)oxy)-2,5,8,11-tetraoxatridecyl)pyridine 
• 128660-97-9 2-(2-(2-(2-((tetrahydro-2H-pyran-2-yl)oxy)ethoxy)ethoxy)ethoxy)ethan-1-ol 
• 3099-28-3 2,6-bis(chloromethyl)pyridine 

Relevant articles and documents

A bi-stable Pt(II) based molecular turnstile

Playing with the competition between H- and coordination-bonds, a bi-stable unsymmetrical organometallic turnstile was designed and its dynamic behaviour was studied in solution using NMR techniques. The turnstile, bearing two differentiated interaction sites, is based on a stator, composed of a square planar Pt(II) centre equipped with one pyridyl group and one phenol moiety, connected to a symmetrical rotor bearing a pyridyl unit as either a H-bond acceptor or as a monodentate coordinating site. Whereas in the absence of a metallic effector, the turnstile is locked by a H-bond formed between the phenol moiety located on the stator and the pyridyl group of the rotor, in the presence of Ag+ cations, the turnstile switches to another closed state resulting from the simultaneous binding of the cations by pyridyl units belonging to both the stator and the rotor. The switching process was shown to be reversible.

A platinum based organometallic turnstile

The synthesis of an organometallic turnstile based on a Pt(ii) centre as a hinge was achieved. Its dynamic behaviour in solution was investigated using 1D and 2D NMR techniques. Using Ag(i) cation as an effector, the switching between its open and closed states in solution was demonstrated. The Royal Society of Chemistry 2013.