1430851-28-7

Basic information

• Product Name: [(4,4′-dimethoxy-2,2′-bipyridine)PtPh₂]
• CAS NO: 1430851-28-7
• Molecular Weight: 565.531
• Mol File: 1430851-28-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(4,4′-dimethoxy-2,2′-bipyridine)PtPh₂](CAS DataBase Reference)
• NIST Chemistry Reference: [(4,4′-dimethoxy-2,2′-bipyridine)PtPh₂](1430851-28-7)
• EPA Substance Registry System: [(4,4′-dimethoxy-2,2′-bipyridine)PtPh₂](1430851-28-7)

Safety Data

• Hazardous Substances Data: 1430851-28-7(Hazardous Substances Data)

Upstream product

• 17217-57-1 4,4'-Dimethoxy-2,2'-bipyridin 

Downstream Products

• 1430851-33-4 [(4,4′-dimethoxy-2,2′-bipyridine)Pt(Ph)(THF)][B(3,5-bis(trifluoromethyl)phenyl)₄] 

Relevant articles and documents

Platinum(II)-catalyzed ethylene hydrophenylation: Switching selectivity between alkyl- and vinylbenzene production

The series of PtII complexes [(xbpy)Pt(Ph)(THF)] [BAr′4] (xbpy =4,4′-X-2,2′-bipyridyl, X = OMe, tBu, H, Br, CO2Et, NO2; Ar′ = 3,5-bis(trifluoromethyl)phenyl) are catalyst precursors for ethylene hydrophenylation. The bipyridyl substituent provides a tunable switch for catalyst selectivity that also has significant influence on catalyst activity and longevity. Less electron donating 4,4′-substituents increase the propensity toward styrene formation over ethylbenzene.