14309-25-2Relevant articles and documents
Controlled synthesis of polyphosphazenes with chain-capping agents
Matyjaszewski, Krzysztof,Montague, Robert A.
, (2021)
N-alkyl phosphoranimines were synthesized via the Staudinger reaction of four different alkyl azides with tris(2,2,2-trifluoroethyl) phosphite. N-adamantyl, N-benzyl, N-t-butyl, and N-trityl phosphoranimines were thoroughly characterized and evaluated as
Molecular batteries based on carbon - Carbon bond formation and cleavage in titanium and vanadium Schiff base complexes
Franceschi, Federico,Solari, Euro,Floriani, Carlo,Rosi, Marzio,Chiesi-Villa, Angiola,Rizzoli, Corrado
, p. 708 - 721 (1999)
The reduction of titanium(III) and vanadium(III) salophen complexes led to the reductive coupling of imino groups in the ligands, and thus to the formation of C-C-bonded dimers which released electrons on subsequent cleavage of the C-C bond. On reduction
Facile Direct Coupling Reactions of MOM-protected Benzylic Alcohols Using Aluminum Chloride
Bui, Tien Tan,Kim, Hee-Kwon
supporting information, p. 1195 - 1198 (2021/08/03)
MOM group is one of the most commonly used protecting groups for alcohols. This study describes novel direct functionalization of the MOM-protected benzylic alcohols. Preparation of allylic compounds from benzyl MOM ethers was successfully achieved by utilization of allyltrimethylsilane and AlCl3. In addition, direct azidation of benzyl MOM ethers using TMSN3 was successful carried out under AlCl3-mediated reaction conditions. These results demonstrate that this novel synthetic procedure is a promising approach to direct functionalization of MOM-protected alcohols including allylation and azidation.
Direct AlCl3-catalyzed transformation of benzyl THP ethers and allyl benzyl ethers
Bui, Tien Tan,Kim, Hee-Kwon
, p. 388 - 397 (2020/10/15)
THP and allyl groups are frequently used for the protection of alcohols. In this study, novel direct transformations of benzyl THP ethers and allyl benzyl ethers, protected forms of alcohols, are reported. TMSN3 and AlCl3 were employ