14310-21-5

Basic information

• Product Name: Benzene, 1-methoxy-4-(2-phenylethyl)-
• Synonyms: Benzene, 1-methoxy-4-(2-phenylethyl)-;1-(4-Methoxyphenyl)-2-phenylethane;1-Methoxy-4-(2-phenylethyl)benzene;1-Methoxy-4-phenethylbenzene;1-Phenethyl-4-methoxybenzene;4-Phenethylanisole
• CAS NO: 14310-21-5
• Molecular Formula: C₁₅H₁₆O
• Molecular Weight: 0
• Mol File: 14310-21-5.mol
• Article Data: 58

Chemical Properties

• Boiling Point: 302.7°Cat760mmHg
• Flash Point: 117.8°C
• Appearance: /
• Density: 1.025g/cm³
• Vapor Pressure: 0.00175mmHg at 25°C
• Refractive Index: 1.56
• CAS DataBase Reference: Benzene, 1-methoxy-4-(2-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(2-phenylethyl)-(14310-21-5)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(2-phenylethyl)-(14310-21-5)

Safety Data

• Hazardous Substances Data: 14310-21-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H16O/c1-16-15-11-9-14(10-12-15)8-7-13-5-3-2-4-6-13/h2-6,9-12H,7-8H2,1H3

Upstream product

• 622-24-2 2-phenylethyl chloride 
• 100-66-3 methoxybenzene 
• 18217-00-0 1-(2-Chloroethyl)-4-methoxybenzene 
• 71-43-2 benzene 
• 1694-19-5 p-methoxystilbene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 100-42-5 styrene 
• 74587-15-8 benzyl 2-(4-methoxyphenyl)ethanoate 
• 63075-63-8 phenylacetic p-methoxyphenylacetic anhydride 
• 29917-69-9 1-(p-methoxyphenyl)-3-phenylpropan-2-one 
• 92014-01-2 2-phenyl-6-methoxybenzothiophene 
• 696-62-8 para-iodoanisole 
• 15207-16-6 Triphenyl-<1-phenyl-2-(4-methoxyphenyl)-aethyl>-phosphoniumbromid 

Downstream Products

• 6335-83-7 4-(2-phenylethyl)phenol 
• 23923-24-2 2,3-bis-(p-methoxyphenyl)-4,5-diphenylcyclopenta-2,4-dienone 
• 1023-17-2 4-methoxyphenyl benzyl ketone 
• 5773-56-8 1,2-Diphenylethanol 
• 5422-47-9 1-(4-methoxyphenyl)-2-phenylethan-1-ol 
• 20498-68-4 1-phenyl-2-(4-methylphenyl)ethanol 
• 21511-90-0 N-(1,2-diphenylethyl)acetamide 
• 133349-91-4 1-(1-(4-methoxyphenyl)-2-phenylethyl)-1H-benzo[d][1,2,3]triazole 
• 93652-27-8 1-(4-methoxyphenyl)-2-phenylethyl acetate 
• 100-52-7 benzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-51-6 benzyl alcohol 
• 23923-26-4 4-Phenyl-2,3,5-tris-(p-anisyl)-(α,α',β)-cyclopentadien-(2,4)-on-(1) 

Relevant articles and documents

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Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.

Aqueous phase semihydrogenation of alkynes over Ni-Fe bimetallic catalysts

Bimetallic Ni-Fe catalysts (Ni/Fe, 1?:?1, 1?:?3, and 3?:?1) are synthesized and explored for their catalytic activity in semihydrogenation of internal alkynes using H2 gas in water-ethanol solution. Our findings revealed that over the Ni1Fe3 catalyst a high diastereoselectivity for Z-alkenes with a high conversion for a wide range of internal alkynes can be achieved at moderate reaction temperature (40 °C). Notably, the selectivity for the Z-alkenes is enhanced in the presence of n-butyl amine as an additive. Deuterium labeling experiments evidenced that H2 gas becomes dissociated homolytically over the catalyst surface to hydrogenate alkynes to alkenes. Synthesized catalysts were successfully characterized by HR-TEM, SEM, XPS, EDS, P-XRD and H2-TPD.