143100-84-9

Upstream product

• 108-24-7 acetic anhydride 
• 143406-44-4 (Z)-3-(tert-Butyl-dimethyl-silanyloxy)-penta-2,4-dienoic acid methyl ester 
• 143406-46-6 5-(1-Hydroxymethyl-cyclohexa-2,5-dienyl)-3-oxo-pentanoic acid methyl ester 
• 143406-45-5 1-(4-Methoxycarbonyl-3-oxo-butyl)-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 143406-50-2 (E)-3-Acetoxy-5-(1-acetoxymethyl-4-oxo-cyclohexa-2,5-dienyl)-pent-2-enoic acid methyl ester 
• 143406-48-8 (E)-3-Acetoxy-5-(1-acetoxymethyl-cyclohexa-2,5-dienyl)-pent-2-enoic acid methyl ester 
• 143406-52-4 (E)-3-Acetoxy-5-(1-acetoxymethyl-4-hydroxy-cyclohexa-2,5-dienyl)-pent-2-enoic acid methyl ester 

Relevant academic research and scientific papers

SYNTHESIS OF cis-DECALIN DERIVATIVE VIA ?-ALLYLPALLADIUM INTERMEDIATE AND ITS TRANSFORMATION TO USEFULLY FUNCTIONALIZED trans-DECALINE DERIVATIVE

Treatment of 15 or 16 with Pd(PPh3)4 (10 mol percent) and NaH (1.2 equiv) afforded the cis-decalin derivative 18 stereoselectively in high yield, which was effectively transformed into the usefully functionalized trans-decalin derivative 29.