1431473-34-5Relevant articles and documents
Ligand-centered redox activity in cobalt(II) and nickel(II) bis(phenolate)-dipyrrin complexes
Kochem, Amélie,Chiang, Linus,Baptiste, Benoit,Philouze, Christian,Leconte, Nicolas,Jarjayes, Olivier,Storr, Tim,Thomas, Fabrice
supporting information, p. 14590 - 14593 (2013/01/15)
One for all: A trianionic ligand containing the biologically relevant moieties phenolate and porphyrin was designed and synthesized. One-electron oxidation of the nickel and cobalt complexes of these ligands affords an unprecedented and highly stable hybrid porphyrinyl-phenoxyl radical bound to the metal center. Two-electron oxidation of these complexes leads to the M 2+-(close-shell two-electron oxidized ligand) species. Copyright