1431569-58-2

Basic information

• Product Name: 5-phenyl-4-(phenyltelluro)selenophene[2,3-b]thiophene
• Synonyms: 5-phenyl-4-(phenyltelluro)selenophene[2,3-b]thiophene
• CAS NO: 1431569-58-2
• Molecular Weight: 466.919
• Mol File: 1431569-58-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-phenyl-4-(phenyltelluro)selenophene[2,3-b]thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenyl-4-(phenyltelluro)selenophene[2,3-b]thiophene(1431569-58-2)
• EPA Substance Registry System: 5-phenyl-4-(phenyltelluro)selenophene[2,3-b]thiophene(1431569-58-2)

Safety Data

• Hazardous Substances Data: 1431569-58-2(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 32294-60-3 diphenyl ditelluride 
• 1218795-31-3 2-(butylselenyl)-3-(phenylethynyl)-thiophene 
• 67237-53-0 3-ethynylthiophene 

Relevant articles and documents

FeCl3-diorganyl dichalcogenides promoted cyclization of 2-organochalcogen-3-alkynylthiophenes: Synthesis of chalcogenophene[2,3-b] thiophenes

We report here our results on the FeCl3-diorganyl dichalcogenides intramolecular cyclization of 2-organochalcogen-3- alkynylthiophenes. The cyclization reaction proceeded cleanly under mild reaction conditions giving the (S)-Se-, (S)-S- and (S)-Te-heterocycles in good yields. In addition, the obtained chalcogenophenes were readily transformed into more complex products using the palladium cross-coupling reaction with boronic acids. Conversely, using a metal-halogen exchange reaction with n-BuLi, the chalcogenophenes produced the lithium-intermediate which was trapped with aldehyde furnishing the desired secondary alcohol in good yield. The Royal Society of Chemistry 2013.