1431571-10-6Relevant articles and documents
Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin
Matsumoto, Arimasa,Oji, Shotaro,Takano, Shizuka,Tada, Kyohei,Kawasaki, Tsuneomi,Soai, Kenso
supporting information, p. 2928 - 2931 (2013/07/26)
Chiral (S)- and (R)-18O-glycerin induces enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, and the subsequent asymmetric autocatalysis affords (R)- and (S)-pyrimidyl alkanol with high enantiomeric excess, respectively.