14316-61-1

Basic information

• Product Name: PHENOXYACETIC ANHYDRIDE
• Synonyms: PHENOXYACETIC ANHYDRIDE;Bis(phenoxyacetic)anhydride;2-Phenoxyacetic anhydride
• CAS NO: 14316-61-1
• Molecular Formula: C₁₆H₁₄O₅
• Molecular Weight: 286.28
• Product Categories: Carbonyl Compounds;Carboxylic Acid Anhydrides;Organic Building Blocks;Building Blocks;Carbonyl Compounds;Carboxylic Acid Anhydrides;Chemical Synthesis;Organic Building Blocks
• Mol File: 14316-61-1.mol
• Article Data: 7

Chemical Properties

• Melting Point: 70-74 °C
• Boiling Point: 427.823 °C at 760 mmHg
• Flash Point: 190.029 °C
• Appearance: /
• Density: 1.234 g/cm³
• Vapor Pressure: 1.59E-07mmHg at 25°C
• Refractive Index: 1.558
• Storage Temp.: Store at RT.
• CAS DataBase Reference: PHENOXYACETIC ANHYDRIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENOXYACETIC ANHYDRIDE(14316-61-1)
• EPA Substance Registry System: PHENOXYACETIC ANHYDRIDE(14316-61-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 10-21
• Hazardous Substances Data: 14316-61-1(Hazardous Substances Data)

Usage

Chemical Properties

Pale yellow liquid

InChI:InChI=1/C16H14O5/c17-15(11-19-13-7-3-1-4-8-13)21-16(18)12-20-14-9-5-2-6-10-14/h1-10H,11-12H2

Upstream product

• 122-59-8 2-phenoxyacetic acid 
• 3598-16-1 2-phenoxyacetic acid sodium salt 
• 701-99-5 Phenoxyacetyl chloride 

Downstream Products

• 228406-34-6 N⁴-phenoxyacetylamino-1-(3,5-di-O-acetyl-2-deoxy-β-D-erythro-pentofuranosyl)-5-methylcytosine 
• 219677-67-5 5'-O-dimethoxytrityl-2'-O,3'-O,6-N-triphenoxyacetyladenosine 
• 190908-02-2 3-methyl-2-(N-phenoxyacetylamino)-5-(2',3,',5'-tri-O-benzyl-β-D-ribofuranosyl)pyridine 
• 183273-93-0 Phenoxy-acetic acid 4,7-bis-{(2-phenoxy-acetyl)-[3-(2-phenoxy-acetylamino)-propyl]-amino}-heptyl ester 
• 154971-68-3 2',3',5'-tris-O-(phenoxyacetyl)adenosine 
• 83167-61-7 Phenoxy-acetic acid (2R,3R,3aR,9aR)-2-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl ester 
• 71674-74-3 6-Cyclohexylsulfanyl-5-fluoro-2,4-dioxo-1-(2-phenoxy-acetyl)-hexahydro-pyrimidine-5-carboxylic acid ethyl ester 
• 71674-71-0 6-Ethoxy-5-fluoro-2,4-dioxo-1-(2-phenoxy-acetyl)-hexahydro-pyrimidine-5-carboxylic acid ethyl ester 
• 142409-72-1 Phenoxy-acetic acid (2R,3S,5R)-2-[bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl ester 
• 143552-42-5 1-(2'-deoxy-β-D-erythro-pentofuranosyl)-4-<(phenoxyacetyl)amino>-1H-pyrrolo<2,3-b>pyridine 
• 137007-48-8 trans-3-Acetyl-4-<2-(tert-butyldimethylsiloxy)ethyl>-5-(methoxycarbonyl)-1-(phenoxyacetyl)-2-pyrroline 
• 137007-49-9 cis-3-Acetyl-4-<2-(tert-butyldimethylsiloxy)ethyl>-5-(methoxycarbonyl)-1-(phenoxyacetyl)-2-pyrroline 

Relevant articles and documents

Low-temperature photosensitized oxidation of a guanosine derivative and formation of an imidazole ring-opened product

An organic-soluble guanosine derivative, 2′,3′,5′-O-(tert-butyldimethylsilyl)guanosine (1), was prepared and its photosensitized oxidation was carried out in several solvents at various temperatures. Singlet oxygen is the reactive oxidizing agent responsi

Simple preparation of symmetrical carboxylic acid anhydrides by means of Na2CO3/SOCl2

A convenient and general method for the synthesis of symmetrical carboxylic acid anhydrides using sodium carbonate/thionyl chloride is described. Copyright Taylor & Francis Group, LLC.

N-PHENOXYACETYLATED GUANOSINE AND ADENOSINE PHOSPHORAMIDITES IN THE SOLID PHASE SYNTHESIS OF OLIGORIBONUCLEOTIDES: SYNTHESIS OF A RIBOZYME SEQUENCE

Phosphoramidites for guanosine and adenosine nucleosides with phenoxyacetyl as N-acyl protecting group were prepared.These nucleoside phosphoramidites, together with previously reported uridine and N-benzoyl cytidine phosphoramidites have been applied to the efficient solid phase synthesis of a trideca and a nonadecaribonucleotide.The later molecule has the sequence corresponding to a ribozyme.