143167-64-0Relevant academic research and scientific papers
Asymmetric Aza-Claisen Rearrangement of Glycolamide and Glycinamide Enolates. Synthesis of Optically Active α-Hydroxy and α-Amino Acids
Tsunoda, Tetsuto,Tatsuki, Shinji,Shiraishi, Yoko,Akasaka, Masumi,Ito, Sho
, p. 3297 - 3300 (1993)
The aza-Claisen rearrangement of the enolates of N-crotyl glycolamide and glycinamide proceeded with excellent syn : anti (98:2) and facial selectivities (89:11).Optically pure (-)-verrucarinolactone and D-allo-isoleucine were derived from the rearrangement products.
