143191-52-0

Basic information

• Product Name: Cyclohexane, 4-(1,1-dimethylethyl)-1,1,2-trimethoxy-, cis-
• CAS NO: 143191-52-0
• Molecular Formula: C13H26O3
• Molecular Weight: 230.348
• Mol File: 143191-52-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 4-(1,1-dimethylethyl)-1,1,2-trimethoxy-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 4-(1,1-dimethylethyl)-1,1,2-trimethoxy-, cis-(143191-52-0)
• EPA Substance Registry System: Cyclohexane, 4-(1,1-dimethylethyl)-1,1,2-trimethoxy-, cis-(143191-52-0)

Safety Data

• Hazardous Substances Data: 143191-52-0(Hazardous Substances Data)

Upstream product

• 36336-08-0 methyl hypofluorite 
• 57466-12-3 4-tert-butyl-1-methoxycyclohexene 
• 98-53-3 4-tercbutyl-cyclohexanone 

Downstream Products

• 35394-07-1 4-tert-butyl-2-methoxycyclohexanone 

Relevant articles and documents

A novel electrophilic methoxylation (with a little help from F2)

Methyl hypofluorite, MeOF, easily made from MeOH and F2, proved to be an excellent source for the novel electrophilic methoxylium ion "MeO+". MeOF was reacted with the enol forms of carbonyls, producing in good to excellent yields the corresponding α-methoxy carbonyl derivatives. It was found that the methoxylation is best carried out on methyl enol ethers. Silyl enol ethers and enol acetates were also tested but with limited success. The reaction proceeds through an addition elimination mechanism.