143206-85-3

Upstream product

• 3111-52-2 potassium thiophenolate 
• 4451-37-0 3,4,6-tri-O-acetyl-β-D-glucopyranosyl chloride 
• 108-98-5 thiophenol 
• 143206-82-0 phenyl 3,4,6-tri-O-acetyl-α-D-gluco-1-thiopyranoside 
• 13871-95-9 cyclohexyloxy(dimethyl)silyl chloride 

Downstream Products

• 61244-31-3 cyclohexyl 3,4,6-tri-O-acetyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Intramolecular Glycosidation: Stereocontrolled Synthesis of α-Glucosides from a 2-O-Alkoxysilyl Thioglucoside

2-O-(Alkoxydimethyl)silylglucosyl piperidide, chloride and thiophenolate derivatives have been prepared, and intramolecular glycosidation of these derivatives was attempted.Reaction of phenyl 3,4,6-tri-O-acetyl-2-O-(octyloxy-, cyclohexyloxy-, tert-butoxy-

Stereocontrolled Synthesis of α-Glucosides by Intramolecular Glycosidation

α-Glucosides are prepared by connecting phenylthio 3,4,6-tri-O-acetyl-α-D-glucopyranoside and an alcohol or a phenol with a dimethylsilylene bridge followed by iodonium ion catalysed intramolecular glycosidation.