1432067-68-9

Basic information

• Product Name: 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione
• Synonyms: 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione
• CAS NO: 1432067-68-9
• Molecular Weight: 606.438
• Mol File: 1432067-68-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione(1432067-68-9)
• EPA Substance Registry System: 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione(1432067-68-9)

Safety Data

• Hazardous Substances Data: 1432067-68-9(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 69595-68-2 1,8-bis(2-bromoethyloxy)-9,10-anthracenedione 

Downstream Products

• 117-10-2 1,8-dihydroxy-9,10-anthracenedione 
• 1432067-84-9 1-hydroxy-8-(2-phenylselenoethoxy)anthracene-9,10-dione 

Relevant articles and documents

Synthesis, reactivity, catenation and X-ray crystallography of Ag + and Cu+ complexes of anthraquinone-based selenoethers: A luminescent chemodosimeter for Cu2+ and Fe3+

Reaction of the PhSe- anion with 1,8-bis(2-bromoethoxy) anthracene-9,10-dione, 1,5-bis(2-bromoethoxy)anthracene-9,10-dione, 1,8-bis(2-bromoethylethyleneoxy)anthracene-9,10-dione in 1:1 ratio generates 1,8-bis(2-phenylselenoethoxy)anthracene-9,10-dione (2), 1,5-bis(2- phenylselenoethoxy)anthracene-9,10-dione (3) and 1,8-bis(2- phenylselenoethylethyleneoxy)anthracene-9,10-dione (4). The reaction of 2 with a methanolic solution of Ag(CH3CN)4BF4 and Cu(CH3CN)4BF4, yielded metal complexes 5 and 6, respectively. 3 formed a 1D coordination polymer (7) with Ag(CH 3CN)4BF4 in a 1:2 ratio. The anthraquinone in 3 exhibits π-π interactions with distances in a range of 3.512-3.840 A?. 2 acts as a chemodosimeter for Cu2+ and Fe3+ as it undergoes an aryl ether cleavage with Cu2+ and Fe3+, and produces the luminescent 1-hydroxy-8-(2-phenylselenoethoxy)anthracene-9,10- dione (8). Intramolecular hydrogen bonding in 8 is responsible for the red-orange (λmax 595 nm) emission. The X-ray structures of 5, 6, 7, and 8 are reported along with cyclic voltammetric analyses of new organoselenium compounds.