1432595-78-2

Basic information

• Product Name: Cbz-(αMe)Val-Aib4-Fib-OMe
• Synonyms: Cbz-(αMe)Val-Aib4-Fib-OMe
• CAS NO: 1432595-78-2
• Molecular Weight: 740.845
• Mol File: 1432595-78-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cbz-(αMe)Val-Aib4-Fib-OMe(CAS DataBase Reference)
• NIST Chemistry Reference: Cbz-(αMe)Val-Aib4-Fib-OMe(1432595-78-2)
• EPA Substance Registry System: Cbz-(αMe)Val-Aib4-Fib-OMe(1432595-78-2)

Safety Data

• Hazardous Substances Data: 1432595-78-2(Hazardous Substances Data)

Upstream product

• 1432595-75-9 H-Aib₃-Fib-OMe 
• 1432595-74-8 H-Aib₂-Fib-OMe 
• 1432595-73-7 H-Aib-Fib-OMe 
• 157337-08-1 methyl 3-fluoro-2-(fluoromethyl)-2-((2-hydroxy-1-phenylethyl)amino)propanoate 
• 1432595-76-0 H-Aib₄-Fib-OMe 
• 137584-40-8 (S)-(+)-2-benzyloxycarbonylamino-2,3-dimethylbutanoic acid 

Relevant articles and documents

Diastereotopic fluorine substituents as 19F NMR probes of screw-sense preference in helical foldamers

Ligating simple amino alcohol or amino ester monomers containing enantiotopic fluorine substituents to the C-terminus of a helical peptide places the fluorine atoms in diastereotopic environments, and gives two distinct and easily identifiable signals in the 19F NMR spectrum. In the case of a dynamically inverting helix built from achiral monomers, the chemical shift separation between the 19F signals provides a simple means of analysing the ratio of screw-sense conformers in the oligomer, in cases where an asymmetric bias leads to a screw-sense preference. The Royal Society of Chemistry 2013.