1433015-86-1Relevant academic research and scientific papers
N-(diazoacetyl)oxazolidin-2-thiones as sulfur-donor reagents: Asymmetric synthesis of thiiranes from aldehydes
Cano, Israel,G?mez-Bengoa, Enrique,Landa, Aitor,Maestro, Miguel,Mielgo, Antonia,Olaizola, Iurre,Oiarbide, Mikel,Palomo, Claudio
, p. 10856 - 10860 (2013/01/15)
Sulfur tyranny: Thiiranes, instead of oxiranes, can be obtained in a highly stereoselective manner through the cycloaddition reaction of N-acyl oxazolidine tethered diazo thione compounds with aldehydes catalyzed by RhII. Thus, this reaction provides versatile adducts S functionalized at both the α and β position, with concomitant generation of two contiguous stereocenters. Copyright
