1433016-21-7

Basic information

• Product Name: (S)-3-((2S,3R)-3-(4-bromophenyl)thiirane-2-carbonyl)-4-isopropyloxazolidin-2-one
• Synonyms: (S)-3-((2S,3R)-3-(4-bromophenyl)thiirane-2-carbonyl)-4-isopropyloxazolidin-2-one
• CAS NO: 1433016-21-7
• Molecular Weight: 370.267
• Mol File: 1433016-21-7.mol

Chemical Properties

• CAS DataBase Reference: (S)-3-((2S,3R)-3-(4-bromophenyl)thiirane-2-carbonyl)-4-isopropyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-((2S,3R)-3-(4-bromophenyl)thiirane-2-carbonyl)-4-isopropyloxazolidin-2-one(1433016-21-7)
• EPA Substance Registry System: (S)-3-((2S,3R)-3-(4-bromophenyl)thiirane-2-carbonyl)-4-isopropyloxazolidin-2-one(1433016-21-7)

Safety Data

• Hazardous Substances Data: 1433016-21-7(Hazardous Substances Data)

Upstream product

• 84272-19-5 (4S)-4-isopropyl-1,3-oxazolidine-2-thione 

Downstream Products

• 17016-83-0 (4S)-4-isopropyl-1,3-oxazolidin-2-one 
• 1433017-70-9 S-((1R,2S)-1-(4-bromophenyl)-1-chloro-3-((S)-4-isopropyl-2-oxooxazolidin-3-yl)-3-oxopropan-2-yl) ethanethioate 
• 1433017-79-8 C₁₇H₁₉BrClNO₄S 

Relevant articles and documents

N-(diazoacetyl)oxazolidin-2-thiones as sulfur-donor reagents: Asymmetric synthesis of thiiranes from aldehydes

Sulfur tyranny: Thiiranes, instead of oxiranes, can be obtained in a highly stereoselective manner through the cycloaddition reaction of N-acyl oxazolidine tethered diazo thione compounds with aldehydes catalyzed by RhII. Thus, this reaction provides versatile adducts S functionalized at both the α and β position, with concomitant generation of two contiguous stereocenters. Copyright