1433206-33-7

Basic information

• Product Name: (E)-4-(prop-1-en-1-yl)oxazolidin-2-one
• CAS NO: 1433206-33-7
• Molecular Weight: 127.143
• Mol File: 1433206-33-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-4-(prop-1-en-1-yl)oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-(prop-1-en-1-yl)oxazolidin-2-one(1433206-33-7)
• EPA Substance Registry System: (E)-4-(prop-1-en-1-yl)oxazolidin-2-one(1433206-33-7)

Safety Data

• Hazardous Substances Data: 1433206-33-7(Hazardous Substances Data)

Upstream product

• 4083-64-1 Tosyl isocyanate 
• 20273-24-9 pent-2-en-1-ol 

Relevant articles and documents

Palladium(II)-catalyzed oxidative cyclization of allylic tosylcarbamates: Scope, derivatization, and mechanistic aspects

A highly selective oxidative palladium(II)-catalyzed (Wacker-type) cyclization of readily available allylic tosylcarbamates is reported. This operationally simple catalytic reaction furnishes tosyl-protected vinyl-oxazolidinones, common precursors to syn-1,2-amino alcohols, in high yield and excellent diasteroselectivity (>20:1). It is demonstrated that both stoichiometric amounts of benzoquinone (BQ) as well as aerobic reoxidation (molecular oxygen) is suitable for this transformation. The title reaction is shown to proceed through overall trans-amidopalladation of the olefin followed by β-hydride elimination. This process is scalable and the products are suitable for a range of subsequent transformations such as: kinetic resolution (KR) and oxidative Heck-, Wacker-, and metathesis reactions.