1433413-25-2Relevant academic research and scientific papers
Regio- and stereoselective allylic C-H arylation with electron-deficient arenes by 1,1′-Bi-2-naphthol-palladium cooperation
Wang, Gang-Wei,Zhou, An-Xi,Li, Shi-Xia,Yang, Shang-Dong
supporting information, p. 3118 - 3121 (2014/06/23)
A palladium-catalyzed allylic C-H arylation reaction with electron-deficient arenes with high regio- and stereoselectivity is reported. This work represents the first successful use of 1,1′-bi-2-naphthol as the ancillary ligand in allylic C-H activation, which is the key factor for chemoselectivity. Furthermore, high selectivity allylic C-H acetoxylation and amination were also successfully achieved under the same catalytic system.
Copper- and phosphine-ligand-free palladium-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides
Yu, Yan-Bo,Fan, Shilu,Zhang, Xingang
supporting information, p. 14643 - 14648 (2013/01/15)
Simply id(all)ylic: A copper- and phosphine-ligand-free Pd-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides and the reaction mechanism are described (see scheme). The simple catalytic system, broad substrate scope,
