143363-76-2Relevant academic research and scientific papers
"Higher Order" Zinc Cuprates Involving Lithium Chloride: Synthesis of (E)-Alkene Dipeptide Isosteres Free from Reductive Elimination Products
Ibuka, Toshiro,Yoshizawa, Hidenori,Habashita, Hiromu,Fujii, Nobutaka,Chounan, Yukiyasu,et al.
, p. 3783 - 3786 (2007/10/02)
The "higher order" organozinc cuprates, R2Cu(CN)(ZnCl)2*2Mg(X)Cl*nLiCl, derived from admixture of LiCl (1-2 equi.), ZnCl2 (1 equiv.), RMgX (1 equiv.), and CuCN (0.5 equiv.) in a mixed solvent of THF and Et2O exhibit high diastereoselection of up to >99:1
