143366-55-6

Basic information

• Product Name: Acetic acid (2R,3R,4R,5S,6S)-2-acetoxymethyl-4-fluoro-6-methoxy-5-(toluene-4-sulfonylamino)-tetrahydro-pyran-3-yl ester
• CAS NO: 143366-55-6
• Molecular Weight: 433.455
• Mol File: 143366-55-6.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid (2R,3R,4R,5S,6S)-2-acetoxymethyl-4-fluoro-6-methoxy-5-(toluene-4-sulfonylamino)-tetrahydro-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2R,3R,4R,5S,6S)-2-acetoxymethyl-4-fluoro-6-methoxy-5-(toluene-4-sulfonylamino)-tetrahydro-pyran-3-yl ester(143366-55-6)
• EPA Substance Registry System: Acetic acid (2R,3R,4R,5S,6S)-2-acetoxymethyl-4-fluoro-6-methoxy-5-(toluene-4-sulfonylamino)-tetrahydro-pyran-3-yl ester(143366-55-6)

Safety Data

• Hazardous Substances Data: 143366-55-6(Hazardous Substances Data)

Upstream product

• 56838-15-4 ((4aR,6S,7R,8R,8aS)-8-Hydroxy-6-methoxy-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid methyl ester 
• 143366-47-6 Methyl 2,3-dideoxy-4,6-O-isopropylidene-2,3-(N-tosylepimino)-α-D-allopyranoside 
• 143366-51-2 Methyl 2,3-dideoxy-2-fluoro-4,6-O-isopropylidene-3-tosylamido-α-D-altropyranoside 
• 143366-45-4 Methyl 2-deoxy-4,6-O-isopropylidene-2-tosylamido-α-D-glucopyranoside 
• 143366-49-8 Methyl 4,6-di-O-acetyl-2,3-dideoxy-2,3-(N-tosylepimino)-α-D-allopyranoside 
• 143366-46-5 Methyl 2-deoxy-4,6-O-isopropylidene-3-O-tosyl-2-tosylamido-α-D-glucopyranoside 
• 120878-43-5 Methyl 2-amino-2-deoxy-4,6-O-isopropylidene-α-D-glucopyranoside 
• 143366-48-7 Methyl 2,3-dideoxy-2,3-(N-tosylepimino)-α-D-allopyranoside 

Relevant articles and documents

Study on fluorination of 2,3-dideoxy-2,3-(N-tosylepimino)-α-D-allopyranosides, and synthesis of 3'-deoxy-3'-fluoro-kanamycin B and 3',4'-dideoxy-3'-fluorokanamycin B

Reaction of the structurally rigid methyl 2,3-dideoxy-4,6-O-isopropylidene-2,3-(N-tosylepimino)-α-D-allopyrano side (6) with KHF2 in DMF at 150° gave initially methyl 2,3-dideoxy-2-fluoro-4,6-O-isopropylidene-3-tosylamido-α-D-altropyra noside (