143370-16-5Relevant academic research and scientific papers
First Example of Reversal of Normal Stereoselectivity in the Intramolecular Pauson-Khand Reaction
Casalnuovo, Joseph A.,Scott, Robert W.,Harwood, Eric A.,Schore, Neil E.
, p. 1153 - 1156 (2007/10/02)
Stereoselectivity favoring exo substituent orientation in the intramolecular Pauson-Khand reaction of 3-methyl-4-hydroxy-1,6-heptenynes to form bicyclooctenones is affected by the relative stereochemistry at C3 and C4.Cycloaddition of one stereoiso
