143393-90-2Relevant academic research and scientific papers
A NEW OXIGENATING METHOD USING 1-ALKOXYCARBONYL-1,2,4-TRIAZOLES AND HYDROGEN PEROXIDE RELATIVE REACTIVITY OF O-ALKYLPEROXYCARBONIC ACIDS
Tsunokawa, Youko,Iwasaki, Shigeo,Okuda, Shigenobu
, p. 4578 - 4581 (2007/10/02)
A convenient method is reported for the epoxidation of alkenes and the Baeyer-Villiger oxidation of a variety of carbonyl compounds using the 1-alkoxycarbonyl-1,2,4-triazoles (1a-c)/H2O2 system.The reactivities of the resulting peroxycarbonic acids were compared.O-Trichloroethylperoxycarbonic acid prepared in this way was isolated as a chloroform solution and was characterized spectroscopically.KEYWORDS - oxygenation with 1-alkoxycarbonyl-1,2,4-triazole/H2O2 system; peroxycarbonic acid; epoxidation; Baeyer-Villiger reaction
