143395-37-3

Upstream product

• 143347-43-7 (1α,5α,7α,8β,12β,13α)-(+/-)-3,6-dioxa-10,10,13-trimethylpentacyclo<11.1.0.0^1,5.0^5,7.0^8,12>tetradecan-2-one 
• 210752-27-5 4,4-dimethyl-2-isopropenylcyclopentylacetic acid 
• 126753-71-7 (+/-)-2-acetyl-4,4-dimethylcyclopentaneacetic acid 
• 104315-18-6 (+/-)-methyl 4,4-dimethyl-2-(1-methylethenyl)cyclopentaneacetate 
• 143347-42-6 (1aα,3aβ,6aβ,6bα)-(+/-)-methyl 2-formyl-3a,4,5,6,6a,6b-hexahydro-5,5,6b-trimethyl-1H-cyclopropindene-1a-carboxylate 
• 126753-75-1 (1aα,3aβ,6aβ,6bα)-(+/-)-methyl 3a,4,5,6,6a,6b-hexahydro-5,5,6b-trimethyl-2<<(trifluoromethyl)sulfonyl>oxy>cyclopropindene-1a(1H)-carboxylate 
• 126753-76-2 (1aα,3aβ,6aβ,6bα)-(+/-)-dimethyl 3a,4,5,6,6a,6b-hexahydro-5,5,6b-trimethylcyclopropindene-1a,2(1H)-dicarboxylate 
• 126753-74-0 (1aα,3aβ,6aβ,6bα)-(+/-)-methyl octahydro-5,5,6b-trimethyl-2-oxopropindene-1a(1H)-carboxylate 
• 126753-73-9 cis-(+/-)-methyl 2,3,3a,6,7,7a-hexahydro-2,2,4-trimethyl-6-oxo-1H-indene-5-carboxylate 
• 143395-41-9 (1α,7β,11β,12α)-(+/-)-3-oxa-9,9,12-trimethyltetracyclo<10.1.0.0^1,5.0^7,11>tridec-5-en-2-one 
• 126753-72-8 (+/-)-4a,5,6,7-tetrahydro-1,6,6-trimethylcyclopentapyran-3(4H)-one 
• 104315-11-9 (E)-5,5,8-Trimethyl-nona-2,7-dienoic acid methyl ester 

Downstream Products

• 82855-02-5 C₁₆H₂₄O₃ 

Relevant academic research and scientific papers

Total Synthesis of Some Marasmane and Lactarane Sesquiterpenes

A general and efficient synthetic route to the marasmane sesquiterpenes (+/-)-isovelleral (2) and (+/-)-stearoylvelutinal (1b) is described.Total syntheses of two other naturally occurring sesquiterpenes, deconjugated anhydrolactarorufin A (5) and lactarorufin A (6), were achieved using an acid-catalyzed ring expansion of lactone 25.All four syntheses are highly stereoselective and do not require the use of any protecting groups.Finally, the protic acid-catalyzed degradation of velutinal (1a) was investigated in an effort to chemically induce the biologically important conversion of velutinal (1a) to isovelleral (2).The experimental results thus obtained indicate that an enzymatic mechanism for the key transformation of velutinal (1a) into isovelleral (2) is more plausible than one that is acid-catalyzed.