1433987-45-1Relevant articles and documents
Pyridine-directed carbon–carbon single bond activation: Rhodium-catalyzed decarbonylation of aryl and heteroaromatic ketones
Johnson, Jeffrey B.,Salisbury, Eric A.,Schoonover, Erik J.,VanderRoest, Jacob P.,Wagner, Cole J.
supporting information, (2021/07/28)
The decarbonylation of 2-pyridyl-substituted ketones via transition metal-catalyzed carbon–carbon bond activation provides ready access to a variety of biaryl compounds. The highly efficient and general method provides reliable decarbonylation of benzophenones including a range of functional groups and substitution patterns. The methodology has also proven highly efficient for heteroaromatic substrates, including those containing thiophenyl, indolyl, quinolinyl, and pyridine substitution.
Acetamide as cocatalyst for the nitrogen-directed coupling of arenes with aryl chlorides through ruthenium-catalyzed c-h activation
Zhang, Jie,Yang, Qin,Zhu, Zhu,Yuan, Mao Lin,Fu, Hai Yan,Zheng, Xue Li,Chen, Hua,Li, Rui Xiang
, p. 6702 - 6706 (2013/01/15)
A simple and highly efficient method for the cross-coupling of aromatics by C-H activation is described. Acetamide was found to be an effective cocatalyst for this generally applicable ruthenium(II)-catalyzed direct arylation reaction. A wide range of dea