143445-66-3Relevant academic research and scientific papers
Ligand-Controlled Direct Hydroformylation of Trisubstituted Olefins
Shin, Taeil,Kim, Hyungsoo,Kim, Sungmin,Lee, Ansoo,Seo, Min-Seob,Choi, Jonghoon,Kim, Hyungjun,Kim, Hyunwoo
supporting information, p. 5789 - 5792 (2019/06/24)
The direct hydroformylation of trisubstituted olefins has been achieved with a combination of a Rh(I) catalyst and a π-acceptor phosphorus (briphos) ligand. A sterically bulky briphos ligand with a large cone angle that forms a 1:1 complex with Rh(I) is found to be reactive for the hydroformylation of trisubstituted olefins. The aldehyde products were obtained with high diastereoselectivity (>99:1) and regioselectivity (49%-81%).
Synthesis and Structure of 2,2'-Dihydroxybenzophenones and 1,8-Dihydroxyfluorenones
Sharma, Vijay,Bachand, Benoit,Simard, Michel,Wuest, James D.
, p. 7785 - 7792 (2007/10/02)
Derivatives of 2,2'-dihydroxybenzophenone and 1,8-dihydroxyfluorenone are interesting because their structures juxtapose a carbonyl group and two hydroxyl groups, thereby permitting them to be used to study the double electrophilic activation of carbonyl
