143553-05-3Relevant articles and documents
Intramolecular Michael-Addition-induced Z→E isomerization of Horner-Emmons reaction products during the synthesis of the N(14)-C(18) subunit of cyclotheonamide A
Roth,Metternich
, p. 3993 - 3996 (1992)
The protected N(14) to C(18) amino acid subunit of cyclotheonamide A has been stereoselectively prepared via Horner-Emmons reaction followed by a novel intramolecular Michael-Addition-induced Z→E isomerization of the α,β-unsaturated carboxylic ester.