143583-01-1Relevant academic research and scientific papers
Oxidative desulfurization-fluorination reaction promoted by [bdmim][F] for the synthesis of difluorinated methyl ethers
Bouvet, Sébastien,Pégot, Bruce,Diter, Patrick,Marrot, Jér?me,Magnier, Emmanuel
, p. 1682 - 1686 (2015/03/14)
A new ionic liquid [bdmim][F] has been prepared and fully characterized. Its potential as a fluoride source for the desulfurization-fluorination process has been evaluated with success. The carbon-sulfur double bond of xanthates and thiocarbonates has bee
Oxidative desulfurization-fluorination of xanthates. A convenient synthesis of trifluoromethyl ethers and difluoro (methylthio)methyl ethers
Kuroboshi, Manabu,Suzuki, Kazundo,Hiyama, Tamejiro
, p. 4173 - 4176 (2007/10/02)
Treatment of xanthates R-OC(S)SMe with (HF)9/Py and 1,3-dibromo-5,5-dimethylhydantoin gives trifluoromethyl ethers R-OCF3 through intermediates R-OCF2SMe, which could be isolated upon treatment of xanthates with n-Bu4N+H2F3- and N-bromosuccinimide.
