1435894-61-3Relevant academic research and scientific papers
Tandem palladium(0) and palladium(II)-catalyzed allylic alkylation through complementary redox cycles
Trost, Barry M.,Thaisrivongs, David A.,Hansmann, Max M.
supporting information, p. 11522 - 11526 (2013/01/15)
Here it goes again: A tandem catalytic process effects sequential Pd 0-catalyzed allylic alkylations through leaving group ionization and PdII-catalyzed allylic alkylations by C-H activation. By employing an oxidative trigger to convert the catalytic species from Pd0 into PdII, both transformations can be conducted in a single reaction vessel using the same precatalyst. This allows for the selective introduction of otherwise indistinguishable allyl groups. Copyright
