1435937-01-1Relevant articles and documents
One click to access push-triazole-pull fluorophores incorporating a pyrimidine moiety: Structure-photophysical properties relationships
Cornec, Anne-Sophie,Baudequin, Christine,Fiol-Petit, Catherine,Ple, Nelly,Dupas, Georges,Ramondenc, Yvan
, p. 1908 - 1915 (2013/05/08)
Using copper-catalysed Huisgen 1,3-dipolar cycloaddition, we describe the synthesis of new A-π-D compounds containing a pyrimidine moiety as π-acceptor (A) and various para-substituted benzene rings as donors (D). Structure-photophysical properties relationships revealed the triazole ring to be a better π-conjugated linker than the triple bond. New push-triazole-pull (pyrimidine-triazole-para-substituted phenyl group) fluorophores were synthesized by using click chemistry, and were found to exhibit interesting photophysical properties.