143601-98-3Relevant academic research and scientific papers
COMPETING RADICAL TRANSLOCATION REACTIONS OF TERTIARY N-(2-BROMOBENZYL)- AND N-(8-BROMONAPHTHYL)-ACETAMIDES
Denenmark, Daniella,Winkler, Tammo,Waldner, Adrian,Mesmaeker, Alain De
, p. 3613 - 3616 (2007/10/02)
The radical translocation reactions in N,N-disubstituted acetamides 10a, 14a - d and trifluoroacetamides 10b, 14e - f have been studied by deuteration experiments with n-Bu3SnD.The intramolecular hydrogen atom transfer from the N-alkyl side chain to the aryl radical takes place through competing 6-, 7-, 8-membered transition states.
