1436383-52-6

Basic information

• Product Name: N-(2’-benzoylphenyl)-4-[2.2]paracyclophanecarboxamide
• CAS NO: 1436383-52-6
• Molecular Weight: 431.534
• Mol File: 1436383-52-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2’-benzoylphenyl)-4-[2.2]paracyclophanecarboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2’-benzoylphenyl)-4-[2.2]paracyclophanecarboxamide(1436383-52-6)
• EPA Substance Registry System: N-(2’-benzoylphenyl)-4-[2.2]paracyclophanecarboxamide(1436383-52-6)

Safety Data

• Hazardous Substances Data: 1436383-52-6(Hazardous Substances Data)

Upstream product

• 20586-49-6 [2.2]paracyclophane-4-carboxylic acid 

Relevant articles and documents

Palladium-catalyzed C-H bond acetoxylation: An approach to ortho-substituted hydroxy[2.2]paracyclophane derivatives

The palladium-catalyzed direct C-H bond acetoxylation of [2.2]paracyclophanes has been investigated. Various mono- and disubstituted [2.2]paracyclophanes were subjected to typical Sanford acetoxylation conditions. Oxime ethers, an oxime acetate, a pyridine, and a pyrazole with [2.2]paracyclophane cores underwent direct ortho-acetoxylation in good to excellent yields using 1-5 mol% of palladium(II) acetate in combination with iodobenzene diacetate as oxidant. The reactions could be performed on a multigram scale, and the ortho-acetoxylated [2.2]paracyclophanes were suitable for further functionalizations affording a hydroxy[2.2]paracyclophane derivative and a planar chiral benzoxazole. Copyright