14366-78-0Relevant articles and documents
Asymmetrically substituted distyrylbenzenes and their polar crystal structures
Collas, Alain,Borger, Roeland De,Amanova, Tatyana,Vande Velde, Christophe M. L.,Baeke, Jan K.,Dommisse, Roger,Alsenoy, Christian Van,Blockhuys, Frank
, p. 649 - 662 (2011/06/20)
The synthesis of twelve asymmetric donor-acceptor distyrylbenzene derivatives with either one nitrile group or one, two or three nitro groups as electron acceptors, and one, two or three methoxy groups as electron donors is reported. Peak potentials obtained from cyclic voltammetry were combined with experimental UV/Vis data and molecular dipole moments obtained from quantum chemical calculations, yielding insight into the influence of the positions of the substituents on the electronic structure and charge distribution of this as yet unexplored class of organic semiconductors. The supramolecular structures of five of these compounds have been studied using single-crystal X-ray diffraction to monitor the influence of the positions of donor and acceptor groups on the organisation of the molecules in the solid state, and three crystal structures have been identified in which the molecular dipoles do not organize themselves in a centrosymmetric lattice. Analysis of the dipoles in the unit cell yields further insight into the possible non-linear optical properties of these three polar structures.
Synthesis and calcium antagonistic activity of diethyl styrylbenzylphosphonates
Younes, S.,Tchani, G.,Baziard-Mouysset, G.,Stigliani, J. L.,Payard, M.,et al.
, p. 87 - 94 (2007/10/02)
Twenty-three new phosphonic ester derivatives of stilbene exhibiting structural analogies with fostedil are described.Examination of calcium antagonism showed that this activity could not be increased by introducing electron-withdrawing, electronreleasing
