143661-35-2

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 121485-05-0 methyl(2R^*,3R^*,4R^*,5R^*)-6-benzyloxy-4,5-epoxy-2-hydroxy-3-methylhexanoate 
• 137532-03-7 (2R^*,3R^*,4R^*,5S^*)-6-benzyloxy-2-hydroxy-5-iodo-3-methyl-4-hexanolide 
• 120506-06-1 isoprpyl (2R^*,3S^*,4E)-6-benzyloxy-2-hydroxy-3-methyl-4-hexenoate 
• 120506-06-1 isopropyl (2S,3R,4E)-6-benzyloxy-2-hydroxy-3-methyl-4-hexenoate 

Downstream Products

• 137532-04-8 (2S,3S)-3-((2S,3R)-3-Benzyloxymethyl-oxiranyl)-2-(tetrahydro-pyran-2-yloxy)-butan-1-ol 
• 137532-04-8 (2R^*,3S^*,4R^*,5R^*)-6-benzyloxy-4,5-epoxy-3-methyl-2-(2-tetrahydropyranyloxy)-1-hexanol 
• 143661-41-0 ethyl (4RS^*,5R^*,6S^*,7S^*,2E)-7,9-isopropylidenedioxy-4-(p-methoxybenzyloxy)-2,6,8-trimethyl-5-(2-tetrahydropyranyloxy)-2-nonenoate 
• 143661-41-0 ethyl (4RS^*,5R^*,6S^*,7S^*,2Z)-7,9-isopropylidenedioxy-4-(p-methoxybenzyloxy)-2,6,8-trimethyl-5-(2-tetrahydropyranyloxy)-2-nonenoate 
• 143661-48-7 (Z)-(5S,6R)-4-(4-Methoxy-benzyloxy)-2-methyl-5-(tetrahydro-pyran-2-yloxy)-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-hept-2-enoic acid 
• 143661-43-2 (5RS^*,6R^*,7S^*,8S^*,9S^*,3Z)-8,10-isopropylidendioxy-5-(p-methoxybenzyloxy)-3,7,9-trimethyl-6-(2-tetrahydropyranyloxy)-3-decen-2-one 
• 143661-40-9 (1RS^*,2R^*,3S^*,4S^*,5S^*)-1-(1,3-dithian-2-yl)-4,6-isopropylidenedioxy-1-(p-methoxybenzyloxy)-3,5-dimethyl-2-(2-tetrahydropyranyloxy)hexane 
• 121485-10-7 (2RS^*,3R^*,4S^*,5S^*,6S^*)-5,7-isopropylidenedioxy-2-(p-methoxybenzyloxy)-4,6-dimethyl-3-(2-tetrahydropyranyloxy)heptanal 
• 143661-36-3 (2R^*,3S^*,4R^*,5R^*)-6-benzyloxy-4,5-epoxy-3-methyl-2-(2-tetrahydropyranyloxy)hexyl pivalate 
• 143661-44-3 (2R^*)-2-<(1S^*,4RS^*,5S^*,6R^*,7R^*)-4-(p-methoxybenzyloxy)-1,2,6-trimethyl-8,9-dioxabicyclo<3.3.1>non-2-en-7-yl>-1-propanol 
• 143661-36-3 2,2-Dimethyl-propionic acid (2S,3S)-3-((2S,3R)-3-benzyloxymethyl-oxiranyl)-2-(tetrahydro-pyran-2-yloxy)-butyl ester 

Relevant academic research and scientific papers

STEREOSELECTIVE SYNTHESIS OF THE (+/-)-IRELAND ALCOHOL

The Ireland alcohol, a key intermediate for the synthesis of tirandamycin A, was prepared in a stereoselective manner, where titanium-mediated Wittig rearrangement and iodolactonization were used as key steps for the construction of four consecutive asymmetric centers.