143668-57-9

Basic information

• Product Name: N,N'-[(1S,2S)-1,2-diphenyl-1,2-ethanediyl]bis[2-(diphenylphosphino)-BenzaMide
• Synonyms: N,N'-[(1S,2S)-1,2-diphenyl-1,2-ethanediyl]bis[2-(diphenylphosphino)-BenzaMide;N,N'-[(1S,2S)-1,2-Diphenyl-1,2-ethanediyl]bis[2- diphenylphosphinobenzamide],99%e.e.
• CAS NO: 143668-57-9
• Molecular Formula: C₅₂H₄₂N₂O₂P₂
• Molecular Weight: 788.849602
• Mol File: 143668-57-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 900.4±65.0 °C(Predicted)
• Appearance: /
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility: Dichloromethane
• PKA: 12.77±0.46(Predicted)
• CAS DataBase Reference: N,N'-[(1S,2S)-1,2-diphenyl-1,2-ethanediyl]bis[2-(diphenylphosphino)-BenzaMide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-[(1S,2S)-1,2-diphenyl-1,2-ethanediyl]bis[2-(diphenylphosphino)-BenzaMide(143668-57-9)
• EPA Substance Registry System: N,N'-[(1S,2S)-1,2-diphenyl-1,2-ethanediyl]bis[2-(diphenylphosphino)-BenzaMide(143668-57-9)

Safety Data

• Hazardous Substances Data: 143668-57-9(Hazardous Substances Data)

Usage

Uses

N,N''-[(1S,2S)-1,2-Diphenyl-1,2-ethanediyl]bis[2-(diphenylphosphino)benzamide is used as a catalyst.

Upstream product

• 17261-28-8 ortho-diphenylphosphinobenzoic acid 
• 35132-20-8 (R,R)-1,2-diphenylethylenediamine 

Relevant articles and documents

A modular approach for ligand design for asymmetric allylic alkylations via enantioselective palladium-catalyzed ionizations

A new class of ligands for asymmetric transition metal catalysis based on 2-(diphenylphosphino)benzoic acid was used in a mechanistically-defined palladium-catalyzed reaction in which enantiodifferentiation was the result of selective ionization of substr