143680-30-2Relevant academic research and scientific papers
Stereoelectronic Control of Facial Selectivity in the Diels-Alder Cycloaddition of Sterically Unbiased 5,5-Diarylcyclopentadienes
Halterman, Ronald L.,McCarthy, Bridget A.,McEvoy, Marjorie A.
, p. 5585 - 5589 (2007/10/02)
This study provides strong evidence for stereoelectronic control of diastereoselectivity in the Diels-Alder cycloaddition of sterically unbiased 5-(4-X-phenyl)-5-phenylcyclopentadienes 1 (X = NO2, Cl, and N(CH3)2) with dimethyl acetylenedicarboxylate (DMA
