143701-53-5Relevant academic research and scientific papers
Reactions of η2-tetracarbonylmanganese complexes derived from podocarpic acid with electrophiles; functionalization of ring C
Cambie, Richard C.,Metzler, Michael R.,Rickard, Clifton E. F.,Rutledge, Peter S.,Woodgate, Paul D.
, p. 177 - 198 (2007/10/02)
Reaction of tetracarbonylmanganese(I) complexes derived from podocarpic acid (1) with electrophilic bromine or iodine in CCl4 leads to 14-halogenated derivatives inaccessible by direct halogenation.Similar reactions in protic solvents lead to the formation of γ-lactones in high yield.The structure of one of these was established unequivocally by X-ray crystallograohy.Attempted oxidation of the C-Mn bond with a number of reagents proved generally to be unsuccessful.
