143708-29-6Relevant articles and documents
Synthesis of 3-nitropyrid-2(1H)-ones from C-nitroacetamide and 1,3-dicarbonyl compounds
Kislyi,Shestopalov,Kagramanov,Semenov
, p. 539 - 542 (1997)
The reaction of nitroacetamide with 1,3-dicarbonyl compounds afforded 3-nitropyrid-2(1H)-ones. The chemical reactivities of nitroacetamide and nitroacetohydrazide were compared.
Synthesis of 3-aminopyridin-2(1H)-ones and 1H-pyrido[2,3-b][1,4]oxazin- 2(3H)-ones
Fisyuk,Kulakov,Goncharov,Nikitina,Bogza,Shatsauskas
, p. 217 - 224 (2014/06/23)
The interaction of 1,3-diketones with chloroacetamide produced N-(3-oxoalkenyl)chloroacetamides. Heating of N-(3-oxoalkenyl)chloroacetamides with an excess of pyridine in ethanol or butanol led to the formation of pyridin-2(1H)-ones, substituted with a py
Hydrogenation on granular palladium-containing catalysts: II. Hydrogenation of nitroheterocyclic compounds
Kislyi,Tolkacheva,Semenov
, p. 269 - 271 (2007/10/03)
Nitroheterocyclic compounds were reduced in a classical reactor with an agitator equipped with a cell for fixed bed of catalyst. As catalysts were applied granular palladium catalysts (0.5% of Pd on γ-Al2O 3 and 2% of Pd on granulated carbon). Anilines and 3-amino-2(1H)-pyridones were obtained in high yield at reduction of the appropriate nitro compounds, and the activity of the catalyst samples only slightly decreased. Yet aminopyrazoles and aminoimidazoles obtained by hydrogenation on palladium were very sensitive to the presence of air even as hydrochlorides. In the course of hydrogenation of nitropyrazoles and nitroimidazoles the activity of the catalyst markedly decreased.